##TITLE=              29Si MAS NMR spectrum of as-synthesized pure silica HPM-1 (with 2-ethyl-1,3,4-trimethylimidazolium fluoride)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Rojas et al. J. Am. Chem. Soc., 135, 11975-11984 (2013) Figure 3
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/08/08 15:32:50
##SOURCE REFERENCE=   STW-29Si-Rojas-2013-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              STW
##NAMES=              HPM-1
##SAMPLE DESCRIPTION= HPM-1, as-made

$$Bibliographic information 
##$AUTHORS=           Rojas, A., Arteaga, O., Kahr, B., Camblor, M.A.
##$TITLE=             Synthesis, structure, and optical activity of HPM-1, a pure silica chiral zeolite
##$JOURNAL=           Journal of the American Chemical Society
##$VOLUME=            135
##$PAGES=             11975-11984
##$YEAR=              2013
##$DOI=               10.1021/ja405088c
##$FIGURE=            Figure 3

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         5
##$PEAK LABELS=        A          B          C          D          E         
##$PEAK TSITES=       
##$PEAK POSITIONS=    -113.643   -106.857   -106.381   -106.038   -105.576   
##$PEAK AREAS=         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        1.34501    1.26779    1.26779    1.26779    1.26779   
##$PEAK SHAPES=        1          1          1          1          1         
##$NUMBERING REF=     
##$ASSIGN REF=        
##$ASSIGN METHOD=     
##$COMMENT=           

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.49
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     10000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -90.14                
##LASTX=              -129.83               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            568
##FIRSTY=              0.02856              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -90.14               0.02856              
 -90.21               0.03175              
 -90.28               0.03190              
 -90.35               0.03192              
 -90.42               0.03154              
 -90.49               0.02409              
 -90.56               0.01776              
 -90.63               0.01371              
 -90.7                0.00707              
 -90.77               0.00304              
 -90.84              -0.00284              
 -90.91              -0.01133              
 -90.98              -0.01355              
 -91.05              -0.02166              
 -91.12              -0.02625              
 -91.19              -0.01797              
 -91.26              -0.01329              
 -91.33              -0.00807              
 -91.4               -0.00004              
 -91.47               0.00260              
 -91.54               0.00259              
 -91.61               0.00253              
 -91.68               0.00304              
 -91.75               0.01154              
 -91.82               0.01850              
 -91.89               0.01854              
 -91.96               0.01863              
 -92.03               0.01875              
 -92.1                0.01297              
 -92.17               0.00453              
 -92.24               0.00261              
 -92.31               0.00239              
 -92.38              -0.00274              
 -92.45              -0.01059              
 -92.52              -0.01344              
 -92.59              -0.01336              
 -92.66              -0.01338              
 -92.73              -0.01336              
 -92.8               -0.01332              
 -92.87              -0.00672              
 -92.94               0.00129              
 -93.01               0.00220              
 -93.08              -0.00378              
 -93.15              -0.01105              
 -93.22              -0.01341              
 -93.29              -0.01339              
 -93.36              -0.01338              
 -93.43              -0.01338              
 -93.5               -0.01338              
 -93.57              -0.01341              
 -93.64              -0.01638              
 -93.71              -0.02249              
 -93.78              -0.02027              
 -93.85              -0.00751              
 -93.92               0.00168              
 -93.99               0.00260              
 -94.06               0.00266              
 -94.13               0.00727              
 -94.2                0.01579              
 -94.27               0.01785              
 -94.34               0.01039              
 -94.41               0.00397              
 -94.48               0.00262              
 -94.55               0.00259              
 -94.62               0.00259              
 -94.69               0.00254              
 -94.76               0.00303              
 -94.83               0.01153              
 -94.9                0.01849              
 -94.97               0.01855              
 -95.04               0.01990              
 -95.11               0.02469              
 -95.18               0.03038              
 -95.25               0.03188              
 -95.32               0.03207              
 -95.39               0.03894              
 -95.46               0.04668              
 -95.53               0.04788              
 -95.6                0.04787              
 -95.67               0.04783              
 -95.74               0.04620              
 -95.81               0.03827              
 -95.88               0.02636              
 -95.95               0.01964              
 -96.02               0.01860              
 -96.09               0.01827              
 -96.16               0.01293              
 -96.23               0.00542              
 -96.3                0.00254              
 -96.37               0.00258              
 -96.44               0.00259              
 -96.51               0.00259              
 -96.58               0.00259              
 -96.65               0.00259              
 -96.72               0.00259              
 -96.79               0.00259              
 -96.86               0.00259              
 -96.93               0.00257              
 -97.                 0.00424              
 -97.07               0.01245              
 -97.14               0.01859              
 -97.21               0.01307              
 -97.28               0.00514              
 -97.35               0.00199              
 -97.42              -0.00231              
 -97.49              -0.00897              
 -97.56              -0.01315              
 -97.63              -0.01342              
 -97.7               -0.01338              
 -97.77              -0.01341              
 -97.84              -0.01310              
 -97.91              -0.00669              
 -97.98               0.00420              
 -98.05               0.01402              
 -98.12               0.01890              
 -98.19               0.02455              
 -98.26               0.03172              
 -98.33               0.03188              
 -98.4                0.03182              
 -98.47               0.02781              
 -98.54               0.02096              
 -98.61               0.01842              
 -98.68               0.01858              
 -98.75               0.01856              
 -98.82               0.01857              
 -98.89               0.01857              
 -98.96               0.01857              
 -99.03               0.01859              
 -99.1                0.01743              
 -99.17               0.01039              
 -99.24               0.00368              
 -99.31               0.00077              
 -99.38              -0.00619              
 -99.45              -0.01310              
 -99.52              -0.01153              
 -99.59              -0.00304              
 -99.66               0.01094              
 -99.73               0.01833              
 -99.8                0.01850              
 -99.87               0.01857              
 -99.94               0.01847              
 -100.01              0.01465              
 -100.08              0.00640              
 -100.15              0.00261              
 -100.22              0.00262              
 -100.29              0.00503              
 -100.36              0.01355              
 -100.43              0.02499              
 -100.5               0.03088              
 -100.57              0.02885              
 -100.64              0.02251              
 -100.71              0.01867              
 -100.78              0.01593              
 -100.85              0.00750              
 -100.92              0.00240              
 -100.99              0.00266              
 -101.06              0.00257              
 -101.13              0.00259              
 -101.2               0.00259              
 -101.27              0.00259              
 -101.34              0.00259              
 -101.41              0.00259              
 -101.48              0.00260              
 -101.55              0.00531              
 -101.62              0.01393              
 -101.69              0.01933              
 -101.76              0.02306              
 -101.83              0.03231              
 -101.9               0.04310              
 -101.97              0.04788              
 -102.04              0.04374              
 -102.11              0.03539              
 -102.18              0.03173              
 -102.25              0.03199              
 -102.32              0.02936              
 -102.39              0.02246              
 -102.46              0.01846              
 -102.53              0.01853              
 -102.6               0.01859              
 -102.67              0.01863              
 -102.74              0.02460              
 -102.81              0.03355              
 -102.88              0.03958              
 -102.95              0.04578              
 -103.02              0.05364              
 -103.09              0.06120              
 -103.16              0.06432              
 -103.23              0.07034              
 -103.3               0.08226              
 -103.37              0.09097              
 -103.44              0.09322              
 -103.51              0.09309              
 -103.58              0.09315              
 -103.65              0.09238              
 -103.72              0.08659              
 -103.79              0.08000              
 -103.86              0.07982              
 -103.93              0.07995              
 -104.                0.08766              
 -104.07              0.10026              
 -104.14              0.11571              
 -104.21              0.13860              
 -104.28              0.16369              
 -104.35              0.18812              
 -104.42              0.20936              
 -104.49              0.23108              
 -104.56              0.25587              
 -104.63              0.28569              
 -104.7               0.31680              
 -104.77              0.36576              
 -104.84              0.43182              
 -104.91              0.49296              
 -104.98              0.56889              
 -105.05              0.64541              
 -105.12              0.70196              
 -105.19              0.77218              
 -105.26              0.84508              
 -105.33              0.90269              
 -105.4               0.96447              
 -105.47              1.03654              
 -105.54              1.10543              
 -105.61              1.16588              
 -105.68              1.2072               
 -105.75              1.26109              
 -105.82              1.30635              
 -105.89              1.33658              
 -105.96              1.37254              
 -106.03              1.39878              
 -106.1               1.417                
 -106.17              1.42858              
 -106.24              1.43022              
 -106.31              1.42755              
 -106.38              1.4156               
 -106.45              1.39793              
 -106.52              1.3687               
 -106.59              1.33278              
 -106.66              1.28212              
 -106.73              1.22173              
 -106.8               1.16744              
 -106.87              1.07249              
 -106.94              0.98586              
 -107.01              0.90294              
 -107.08              0.81397              
 -107.15              0.77333              
 -107.22              0.70999              
 -107.29              0.64980              
 -107.36              0.60186              
 -107.43              0.55968              
 -107.5               0.52375              
 -107.57              0.48182              
 -107.64              0.44700              
 -107.71              0.42043              
 -107.78              0.39392              
 -107.85              0.37031              
 -107.92              0.35013              
 -107.99              0.32771              
 -108.06              0.30370              
 -108.13              0.27971              
 -108.2               0.26136              
 -108.27              0.2451               
 -108.34              0.2287               
 -108.41              0.22188              
 -108.48              0.21922              
 -108.55              0.21205              
 -108.62              0.20632              
 -108.69              0.20503              
 -108.76              0.20377              
 -108.83              0.19747              
 -108.9               0.19073              
 -108.97              0.18751              
 -109.04              0.17517              
 -109.11              0.16235              
 -109.18              0.15808              
 -109.25              0.15679              
 -109.32              0.15034              
 -109.39              0.14379              
 -109.46              0.14293              
 -109.53              0.13418              
 -109.6               0.12733              
 -109.67              0.12391              
 -109.74              0.11594              
 -109.81              0.11156              
 -109.88              0.10608              
 -109.95              0.09389              
 -110.02              0.08324              
 -110.09              0.07126              
 -110.16              0.05946              
 -110.23              0.05384              
 -110.3               0.05910              
 -110.37              0.06392              
 -110.44              0.06379              
 -110.51              0.06378              
 -110.58              0.06395              
 -110.65              0.05850              
 -110.72              0.05019              
 -110.79              0.04782              
 -110.86              0.04786              
 -110.93              0.04798              
 -111.                0.04957              
 -111.07              0.05281              
 -111.14              0.05324              
 -111.21              0.05369              
 -111.28              0.06060              
 -111.35              0.06393              
 -111.42              0.06367              
 -111.49              0.06474              
 -111.56              0.07377              
 -111.63              0.07998              
 -111.7               0.07976              
 -111.77              0.07983              
 -111.84              0.07977              
 -111.91              0.08466              
 -111.98              0.09142              
 -112.05              0.09372              
 -112.12              0.10412              
 -112.19              0.11713              
 -112.26              0.12425              
 -112.33              0.12755              
 -112.4               0.12777              
 -112.47              0.13030              
 -112.54              0.13942              
 -112.61              0.15105              
 -112.68              0.16694              
 -112.75              0.18174              
 -112.82              0.20486              
 -112.89              0.23719              
 -112.96              0.26418              
 -113.03              0.28919              
 -113.1               0.32054              
 -113.17              0.3522               
 -113.24              0.38308              
 -113.31              0.41138              
 -113.38              0.43565              
 -113.45              0.45471              
 -113.52              0.46904              
 -113.59              0.48005              
 -113.66              0.47721              
 -113.73              0.46978              
 -113.8               0.45876              
 -113.87              0.43984              
 -113.94              0.41098              
 -114.01              0.38368              
 -114.08              0.35578              
 -114.15              0.32781              
 -114.22              0.29702              
 -114.29              0.26792              
 -114.36              0.24465              
 -114.43              0.21952              
 -114.5               0.20084              
 -114.57              0.18380              
 -114.64              0.17465              
 -114.71              0.17120              
 -114.78              0.16256              
 -114.85              0.15257              
 -114.92              0.14082              
 -114.99              0.12821              
 -115.06              0.11965              
 -115.13              0.10582              
 -115.2               0.09081              
 -115.27              0.07928              
 -115.34              0.06981              
 -115.41              0.06051              
 -115.48              0.04806              
 -115.55              0.03807              
 -115.62              0.02896              
 -115.69              0.02372              
 -115.76              0.02396              
 -115.83              0.02388              
 -115.9               0.02390              
 -115.97              0.02389              
 -116.04              0.02388              
 -116.11              0.02501              
 -116.18              0.03048              
 -116.25              0.03603              
 -116.32              0.03988              
 -116.39              0.04811              
 -116.46              0.04661              
 -116.53              0.03922              
 -116.6               0.03699              
 -116.67              0.03132              
 -116.74              0.02409              
 -116.81              0.02390              
 -116.88              0.02300              
 -116.95              0.01563              
 -117.02              0.01165              
 -117.09              0.01943              
 -117.16              0.02396              
 -117.23              0.02003              
 -117.3               0.00913              
 -117.37             -0.00723              
 -117.44             -0.02688              
 -117.51             -0.03759              
 -117.58             -0.03731              
 -117.65             -0.03695              
 -117.72             -0.03125              
 -117.79             -0.02543              
 -117.86             -0.02403              
 -117.93             -0.02403              
 -118.               -0.02404              
 -118.07             -0.02192              
 -118.14             -0.01338              
 -118.21             -0.00779              
 -118.28             -0.00809              
 -118.35             -0.00479              
 -118.42              0.00192              
 -118.49              0.00657              
 -118.56              0.00788              
 -118.63              0.00792              
 -118.7               0.00792              
 -118.77              0.00791              
 -118.84              0.00792              
 -118.91              0.00792              
 -118.98              0.00792              
 -119.05              0.00792              
 -119.12              0.00792              
 -119.19              0.00792              
 -119.26              0.00792              
 -119.33              0.00792              
 -119.4               0.00790              
 -119.47              0.00801              
 -119.54              0.00750              
 -119.61              0.00353              
 -119.68             -0.00319              
 -119.75             -0.00798              
 -119.82             -0.00262              
 -119.89              0.00790              
 -119.96              0.01630              
 -120.03              0.02230              
 -120.1               0.02407              
 -120.17              0.02231              
 -120.24              0.01505              
 -120.31              0.00386              
 -120.38             -0.00546              
 -120.45             -0.00806              
 -120.52             -0.00806              
 -120.59             -0.01042              
 -120.66             -0.01913              
 -120.73             -0.02399              
 -120.8              -0.01760              
 -120.87             -0.01050              
 -120.94             -0.00768              
 -121.01             -0.00081              
 -121.08              0.00778              
 -121.15              0.00579              
 -121.22             -0.00271              
 -121.29             -0.00825              
 -121.36             -0.00501              
 -121.43              0.00444              
 -121.5               0.01663              
 -121.57              0.02865              
 -121.64              0.03688              
 -121.71              0.03724              
 -121.78              0.03722              
 -121.85              0.03547              
 -121.92              0.02816              
 -121.99              0.02370              
 -122.06              0.02389              
 -122.13              0.01864              
 -122.2               0.01064              
 -122.27              0.00783              
 -122.34              0.01182              
 -122.41              0.02019              
 -122.48              0.02402              
 -122.55              0.02379              
 -122.62              0.01987              
 -122.69              0.01034              
 -122.76             -0.00072              
 -122.83             -0.00778              
 -122.9              -0.00447              
 -122.97              0.0039               
 -123.04              0.01659              
 -123.11              0.02824              
 -123.18              0.03443              
 -123.25              0.03837              
 -123.32              0.04544              
 -123.39              0.04814              
 -123.46              0.04185              
 -123.53              0.03728              
 -123.6               0.03721              
 -123.67              0.03724              
 -123.74              0.03693              
 -123.81              0.03132              
 -123.88              0.02498              
 -123.95              0.02157              
 -124.02              0.01470              
 -124.09              0.00823              
 -124.16              0.00788              
 -124.23              0.00791              
 -124.3               0.00792              
 -124.37              0.00791              
 -124.44              0.00792              
 -124.51              0.00792              
 -124.58              0.00792              
 -124.65              0.00792              
 -124.72              0.00792              
 -124.79              0.00792              
 -124.86              0.00791              
 -124.93              0.00794              
 -125.                0.00777              
 -125.07              0.00855              
 -125.14              0.01437              
 -125.21              0.02095              
 -125.28              0.02375              
 -125.35              0.02392              
 -125.42              0.02389              
 -125.49              0.02389              
 -125.56              0.02390              
 -125.63              0.02386              
 -125.7               0.02620              
 -125.77              0.03366              
 -125.84              0.04498              
 -125.91              0.05793              
 -125.98              0.06691              
 -126.05              0.06917              
 -126.12              0.06916              
 -126.19              0.06924              
 -126.26              0.06876              
 -126.33              0.06108              
 -126.4               0.04963              
 -126.47              0.03849              
 -126.54              0.02797              
 -126.61              0.02398              
 -126.68              0.01985              
 -126.75              0.01148              
 -126.82              0.00778              
 -126.89              0.00797              
 -126.96              0.00786              
 -127.03              0.00795              
 -127.1               0.00769              
 -127.17              0.00256              
 -127.24             -0.00584              
 -127.31             -0.00806              
 -127.38             -0.00805              
 -127.45             -0.00806              
 -127.52             -0.00805              
 -127.59             -0.00805              
 -127.66             -0.00805              
 -127.73             -0.00805              
 -127.8              -0.00805              
 -127.87             -0.00805              
 -127.94             -0.00805              
 -128.01             -0.00805              
 -128.08             -0.00805              
 -128.15             -0.00806              
 -128.22             -0.00805              
 -128.29             -0.00621              
 -128.36              0.00077              
 -128.43              0.01309              
 -128.5               0.02182              
 -128.57              0.02391              
 -128.64              0.02389              
 -128.71              0.02387              
 -128.78              0.02403              
 -128.85              0.02385              
 -128.92              0.01689              
 -128.99              0.00846              
 -129.06              0.00782              
 -129.13              0.00792              
 -129.2               0.00794              
 -129.27              0.01049              
 -129.34              0.01852              
 -129.41              0.02366              
 -129.48              0.02389              
 -129.55              0.02392              
 -129.62              0.02347              
 -129.69              0.01765              
 -129.76              0.00785              
 -129.83             -0.00272              
##END=
